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Synthesis and characterization of 4-aryl substituted silicon-nitrogen-boron and silicon-nitrogen systems
Hauger, Kyralyssa Elayne
Hauger, Kyralyssa Elayne
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Date
2016
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Abstract
The Neilson group has developed a broad spectrum of derivative chemistry originating from the study of boron compounds containing silicon-nitrogen functional groups. Some of our current research interests have focused on investigating compounds containing Si-N moieties attached to a 4-substituted aryl (Ar) functionality to afford silylanilino derivatives. Due to the variety of reactions that can occur at the boron center, combined with the reactivity of the Si-N bond, some of these compounds have the potential to be precursors to new cyclic and/or polymeric systems, for example poly(phenylene-borazenes), i.e. new inorganic-organic hybrid polymers in which the borazene (-BR-NR-) and arylene (-C6H4-) units alternate along the backbone. The work to be presented focuses on the synthesis, characterization and reactivity of some representative examples of 4-aryl substituted (silylanilino)boranes. To be discussed are two classes of title compounds of type I, (silylanilino)boranes with the Ar-N-B backbone, and type II, (silylanilino)boranes with the B-Ar-N backbone. With
Contents
Subject
Subject(s)
Boron compounds.
Silicon.
Nitrogen.
Inorganic compounds Synthesis.
Silicon.
Nitrogen.
Inorganic compounds Synthesis.
Research Projects
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Genre
Dissertation
Description
Format
1 online resource (xi, 177 pages) :
Department
Chemistry and Biochemistry