Loading...
Palladium-Catalyzed Allylation/Benzylation of H-Phosphinate Esters with Alcohols
Citations
Altmetric:
Soloist
Composer
Publisher
Multidisciplinary Digital Publishing Institute
Date
2016-09-28
Additional date(s)
Abstract
The Pd-catalyzed direct alkylation of H-phosphinic acids and hypophosphorous acid with allylic/benzylic alcohols has been described previously. Here, the extension of this methodology to H-phosphinate esters is presented. The new reaction appears general, although its scope is narrower than with the acids, and its mechanism is likely different. Various alcohols are examined in their reaction with phosphinylidene compounds R1R2P(O)H.
Contents
Subject(s)
Research Projects
Organizational Units
Journal Issue
Genre
Description
Format
Department
Chemistry and Biochemistry