Hexadecyl-Containing Organic Salts as Novel Organogelators for Ionic, Eutectic, and Molecular Liquids

Prieto Kullmer, Cesar N.; Ta, Daniel; Chen, Christian Y.; Cieker, Christopher J.; Annunziata, Onofrio; Dzyuba, Sergei V.

Publication

Hexadecyl-Containing Organic Salts as Novel Organogelators for Ionic, Eutectic, and Molecular Liquids

Prieto Kullmer, Cesar N.; Ta, Daniel; Chen, Christian Y.; Cieker, Christopher J.; Annunziata, Onofrio; Dzyuba, Sergei V.

Publisher

American Chemical Society

Date

2019-05-29

Abstract

The incorporation of a hexadecyl group on imidazolium, pyridinium, and pyrrolidinium scaffolds produces low-molecular-weight ionic organogelators that can gel several types of ionic liquids, deep eutectic solvents (DESs), and several molecular organic solvents. Minimum gelator concentrations fall in the 0.9-15.0% (w/v) range, with the lower end of the gelator concentrations observed in the gelation of DESs. On the basis of polarized optical microscopy, differential scanning calorimetry, and X-ray data, crystallization of these salts appear to produce high-surface-area crystals, which generate sufficiently stable three-dimensional networks that are capable of trapping the solvent molecules. Importantly, the nature of the fluid component of the gel appears to have a profound effect on the morphology of the crystallized organogelators. On the other hand, the organogelators appeared to modulate phase transitions of the liquids.