dc.creator | Prieto Kullmer, Cesar N. | |
dc.creator | Ta, Daniel | |
dc.creator | Chen, Christian Y. | |
dc.creator | Cieker, Christopher J. | |
dc.creator | Annunziata, Onofrio | |
dc.creator | Dzyuba, Sergei V. | |
dc.date.accessioned | 2019-07-11T15:17:10Z | |
dc.date.available | 2019-07-11T15:17:10Z | |
dc.date.issued | 2019-05-29 | |
dc.identifier.uri | https://doi.org/10.1021/acsomega.9b00038 | |
dc.identifier.uri | https://repository.tcu.edu/handle/116099117/26384 | |
dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acsomega.9b00038 | |
dc.description.abstract | The incorporation of a hexadecyl group on imidazolium, pyridinium, and pyrrolidinium scaffolds produces low-molecular-weight ionic organogelators that can gel several types of ionic liquids, deep eutectic solvents (DESs), and several molecular organic solvents. Minimum gelator concentrations fall in the 0.9-15.0% (w/v) range, with the lower end of the gelator concentrations observed in the gelation of DESs. On the basis of polarized optical microscopy, differential scanning calorimetry, and X-ray data, crystallization of these salts appear to produce high-surface-area crystals, which generate sufficiently stable three-dimensional networks that are capable of trapping the solvent molecules. Importantly, the nature of the fluid component of the gel appears to have a profound effect on the morphology of the crystallized organogelators. On the other hand, the organogelators appeared to modulate phase transitions of the liquids. | |
dc.language.iso | en | en_US |
dc.publisher | American Chemical Society | |
dc.rights.uri | https://pubs.acs.org/page/policy/authorchoice_termsofuse.html | |
dc.source | ACS Omega | |
dc.subject | Salts | |
dc.subject | Anions | |
dc.subject | Gelation | |
dc.subject | Gels | |
dc.subject | Solvents | |
dc.title | Hexadecyl-Containing Organic Salts as Novel Organogelators for Ionic, Eutectic, and Molecular Liquids | |
dc.type | Article | |
dc.rights.holder | Kullmer et al. | |
dc.rights.license | This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes. | |
local.college | College of Science and Engineering | |
local.department | Chemistry and Biochemistry | |
local.persons | All (CHEM) | |