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dc.contributor.advisorGraham, W. R. M.
dc.contributor.authorHuang, Jiunwoeien_US
dc.date.accessioned2019-10-11T15:11:12Z
dc.date.available2019-10-11T15:11:12Z
dc.date.created1990en_US
dc.date.issued1990en_US
dc.identifieraleph-366627en_US
dc.identifierMicrofilm Diss. 538en_US
dc.identifier.urihttps://repository.tcu.edu/handle/116099117/34129
dc.description.abstractAn FTIR study of tricarbon hydrides has been carried out by trapping the products of the vacuum uv photolysis of methylacetylene, allene, cyclopropane, and their deuterated precursors, in solid argon at 10 K. Stable, partially deuterated tricarbon hydride molecules have been identified, based on available matrix and gas phase data and by using the Wilson GF matrix method to determine the vibrations of partially deuterated isotomers of the molecules. The results reveal new information on the vibrations for 10 species of tricarbon hydrides, including two C$\sb3$H isomers, linear C$\sb3$H (propenylidyne) and cyclic C$\sb3$H; five C$\sb3$H$\sb2$ isomers, cyclopropenylidene, vinylidenecarbene, propargylene, trans-propenediylidene, and cis-propenediylidene; two C$\sb3$H$\sb3$ isomers, propargyl and cyclopropenyl; and one C$\sb3$H$\sb5$ isomer, allyl. (Abstract shortened with permission of author.)
dc.format.extentxiv, 136 leaves : illustrationsen_US
dc.format.mediumFormat: Printen_US
dc.language.isoengen_US
dc.relation.ispartofTexas Christian University dissertationen_US
dc.relation.ispartofAS38.H71en_US
dc.subject.lcshHydrides--Photochemistryen_US
dc.titleFTIR study of tricarbon hydrides in solid argon at 10 Ken_US
dc.typeTexten_US
etd.degree.departmentDepartment of Physics and Astronomy
etd.degree.levelDoctoral
local.collegeCollege of Science and Engineering
local.departmentPhysics and Astronomy
local.academicunitDepartment of Physics and Astronomy
dc.type.genreDissertation
local.subjectareaPhysics and Astronomy
dc.identifier.callnumberMain Stacks: AS38 .H71 (Regular Loan)
dc.identifier.callnumberSpecial Collections: AS38 .H71 (Non-Circulating)
etd.degree.nameDoctor of Philosophy
etd.degree.grantorTexas Christian University


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