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Conformational preference of a porphyrin rotor in confined environments
Jameson, Laramie P. Balaz, Milan Dzyuba, Sergei V. Kamiya, Noriho
Jameson, Laramie P.
Balaz, Milan
Dzyuba, Sergei V.
Kamiya, Noriho
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The Royal Society of Chemistry
Date
2013-11-05
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Abstract
The amount of twisted conformation of a porphyrin rotor, when confined within ionic liquid reverse micelles, increased as compared to the neat solvents within a set of 1-alkyl-3-methylimidazolium ionic liquids. A similar trend was noted within DMSO-containing reverse micelles, indicating that the confinement might be a major contributor in the control of the rotor's conformation.
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ionic liquids
solvents
solvents
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Chemistry and Biochemistry