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Mechanothermally induced conformational switch of a porphyrin dimer in a polymer film

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The Royal Society of Chemistry
Date
2016-06-07
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Abstract
Stretching a polymer film induces a conformational change (from the twisted to planar state) in the embedded porphyrin dimer, as evidenced by steady-state and time-resolved emission spectra.
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Subject
Photophysical properties
 mechanical-properties
 poly(vinyl alcohol)
 transition moments
 covalent bonds
 excited-state
 cross-linking
 spectroscopy
 mechanochemistry
 orientation
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Physics and Astronomy
Chemistry and Biochemistry
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URI
https://repository.tcu.edu/handle/116099117/11214
 https://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC04306B
DOI
https://doi.org/10.1039/C6CC04306B