Fourier transform infrared spectroscopic and density functional theoretical studies of silicon-carbon molecules [electronic resource] /Show full item record
|Title||Fourier transform infrared spectroscopic and density functional theoretical studies of silicon-carbon molecules [electronic resource] /|
|Author||Lê, Tina Huong|
|Description||Title from dissertation title page (viewed Jun. 12, 2014).
Thesis (Ph.D.)--Texas Christian University, 2014.
Department of Physics and Astronomy; advisors, W. R. M. Graham, C. M. L. Rittby.
Includes bibliographical references.
Text (electronic thesis) in PDF.
Astronomers, experimentalists and theorists have produced a great deal of research on SinCm species, because of their potential applications to astrophysics and the study of Group IV molecules. The present work is part of this on-going research and we report here, the synthesis and observation of vibrational fundamentals of silicon-carbon species, SiC5 and SiC5Si. The infrared spectrum of SiC5 was observed by trapping the vapor from the Nd:YAG laser ablation of sintered Si/C rods in solid Ar at ~20 K. Measurements of ¹³C and ²¿,³°Si isotopic shifts have enabled the identification of the v4(s) vibrational fundamental of the linear isomer of SiC5Si at 936.9 ± 0.2 cm¿¹.The observed isotopic shifts are in excellent agreement with the predictions of DFT (density functional theory) calculations at the B3LYP/cc-pVDZ level. SiC5Si was produced using argon matrix trapping and Nd:YAG laser ablation of a sintered 30% Si/ 70%¹²C rod in solid Ar at ~20 K. The ¹³C and ²¿,³°Si isotopic shifts were observed, and upon comparison with the calculations of DFT-B3LYP/cc-pVDZ, are in excellent agreement. This leads to a confident identification of the v5(s¿) fundamental of linear SiC5Si at 1590.8 ± 0.2 cm¿¹. A second fundamental, v4(s¿), can only be tentatively identified at 2021.0 cm¿¹ because near-lying absorptions belonging to other species overlap its isotopic shift pattern.
|Subject||Fourier transform spectroscopy.
This item appears in the following Collection(s)
- Theses and Dissertations