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dc.contributor.authorHolley, Woodrow Wilsonen_US
dc.date.accessioned2019-10-11T15:10:01Z
dc.date.available2019-10-11T15:10:01Z
dc.date.created1980en_US
dc.date.issued1980en_US
dc.identifieraleph-254763en_US
dc.identifier.urihttps://repository.tcu.edu/handle/116099117/31771
dc.description.abstractThe synthesis and structures of four copper(II) dipivaloylmethane (DPM) complexes; Cu(DPM)(,2), Cu(,4)(OCH(,3))(,4)(DPM)(,4), Cu(,4)(O)(Pz)(,2)(DPM)(,4), and Cu(,9)(OHO)(OH)(,6)(DPM)(,9); are presented. The relationship between the structural geometry of these complexes and their magnetic behavior is also discussed. The Cu(DPM)(,2) complex is square planar. The Cu(,4)(OCH(,3))(,4)(DPM)(,4) structure is that of a step tetramer, while that of Cu(,4)(O)(Pz)(,2)(DPM)(,4) is a (mu)(,4)-oxo bridged complex with tetrahedral symmetry. The Cu(,9)(OHO)(OH)(,6)(DPM)(,9) structure has the overall geometry of a triangular prism. Reasons for the inconstant structural types for these and other known Cu(II)-DPM complexes are also examined. In addition, the synthesis and structure of tetrapyrazole copper(II) nitrate, Cu(Pz)(,2)(NO(,3))(,2), and (mu)(,4)-oxo-hexa-(mu)-bromo-tetrakis-{(3-quinulidione) copper(II)}, Cu(,4)(O)Br(,6)(3-quin)(,4) are presented. The structure of Cu(Pz)(,4)(NO(,3))(,2) is that of a distorted octahedron. The copper arrangement for Cu(,4)(O)Br(,6)(3-quin)(,4) is that of a regular tetrahedron.en_US
dc.format.extentvii, 117 leaves, bound : illustrationsen_US
dc.format.mediumFormat: Printen_US
dc.language.isoengen_US
dc.relation.ispartofTexas Christian University dissertationen_US
dc.relation.ispartofAS38.H61en_US
dc.subject.lcshCopper--Magnetic propertiesen_US
dc.subject.lcshCopper compoundsen_US
dc.titleSynthesis, structure, and magnetism of some polynuclear copper (II) complexesen_US
dc.typeTexten_US
etd.degree.departmentDepartment of Chemistry
etd.degree.levelDoctoral
local.collegeCollege of Science and Engineering
local.departmentChemistry and Biochemistry
local.academicunitDepartment of Chemistry
dc.type.genreDissertation
local.subjectareaChemistry and Biochemistry
dc.identifier.callnumberMain Stacks: AS38 .H61 (Regular Loan)
dc.identifier.callnumberSpecial Collections: AS38 .H61 (Non-Circulating)
etd.degree.nameDoctor of Philosophy
etd.degree.grantorTexas Christian University


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