Synthesis and carbon tetrachloride reactions of (silylamino)phosphinesShow simple item record
dc.contributor.advisor | Neilson, Robert H. | |
dc.contributor.author | Ford, Randal Ray | en_US |
dc.date.accessioned | 2019-10-11T15:10:02Z | |
dc.date.available | 2019-10-11T15:10:02Z | |
dc.date.created | 1984 | en_US |
dc.date.issued | 1984 | en_US |
dc.identifier | aleph-232763 | en_US |
dc.identifier.uri | https://repository.tcu.edu/handle/116099117/31782 | |
dc.description.abstract | In Section I, the reactions of a series of (silylamino)phosphines, (Me(,3)Si)(,2)NP(R)CHR'R'', with CCl(,4) are discussed. In general, two major reaction pathways are accessible for these reactions. Reaction pathway A involves removal of an (alpha) proton to produce an ylide intermediate, which then rearranges via a {1,3}-silyl migration to yield the corresponding P-chloro iminophosphorane, Me(,3)SiN=P(R)(Cl)-C(SiMe(,3))R'R'', in which the (alpha) carbon has become silylated. Reaction pathway B involves cleavage of a silicon-nitrogen bond by the CCl(,3)('-) anion to produce a P-chloro iminophosphorane, Me(,3)SiN=P(R)(Cl)-CHR'R'', which has one less silyl group. The factors which influence the course of such reactions are also discussed. In Section II, the preparation of a series of (Me(,3)Si)(,2)CH substituted (silylamino)phosphines, (Me(,3)Si)(,2)NP(R)CH(SiMe(,3))(,2), and, when applicable, their reactions with CCl(,4), are described. These phosphines showed varied reactivity which depended upon the other substituent (R) on phosphorus and/or the reaction conditions employed. | |
dc.format.extent | v, 105 leaves, bound | en_US |
dc.format.medium | Format: Print | en_US |
dc.language.iso | eng | en_US |
dc.relation.ispartof | Texas Christian University dissertation | en_US |
dc.relation.ispartof | AS38.F61 | en_US |
dc.subject.lcsh | Carbon tetrachloride | en_US |
dc.subject.lcsh | Silylaminophosphines | en_US |
dc.title | Synthesis and carbon tetrachloride reactions of (silylamino)phosphines | en_US |
dc.type | Text | en_US |
etd.degree.department | Department of Chemistry | |
etd.degree.level | Doctoral | |
local.college | College of Science and Engineering | |
local.department | Chemistry and Biochemistry | |
local.academicunit | Department of Chemistry | |
dc.type.genre | Dissertation | |
local.subjectarea | Chemistry and Biochemistry | |
dc.identifier.callnumber | Main Stacks: AS38 .F61 (Regular Loan) | |
dc.identifier.callnumber | Special Collections: AS38 .F61 (Non-Circulating) | |
etd.degree.name | Doctor of Philosophy | |
etd.degree.grantor | Texas Christian University |
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Doctoral Dissertations [1523]