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dc.contributor.advisorGraham, W. R. M.
dc.contributor.authorGonzalez, Ericen_US
dc.date.accessioned2014-07-22T18:47:38Z
dc.date.available2014-07-22T18:47:38Z
dc.date.created2009en_US
dc.date.issued2009en_US
dc.identifieretd-10162009-130952en_US
dc.identifierumi-10081en_US
dc.identifiercat-001495726en_US
dc.identifier.urihttps://repository.tcu.edu:443/handle/116099117/4139
dc.description.abstractThis research involved the formation of novel molecules, and the first observation of infrared active modes and infrared active combination bands of already discovered molecules. The molecules were produced by the laser evaporation of germanium, germanium-carbon, and carbons rod previously sintered in a new built vacuum furnace. The infrared spectra were taken using Bomem FTIR spectrometer with an interface infrared optics toward the formation chamber. These molecules were theoretically simulated using commercial quantum chemistry suites of programs and homemade codes. The linear GeC5Ge germanium-carbon chain has been detected for the first time through the dual laser evaporation of graphite and germanium, the ?4(su) vibrational fundamental was observed at 2158.0 cm-1. Two new vibrational fundamentals of linear GeC3Ge, ?4(su = 735.3 cm-1 and ?6(pu) = 580.1 cm-1, have been observed.^This is apparently the first observation of germanium isotopic shifts in vibrational spectra.^Linear GeC3 has been formed by the dual laser ablation of germanium and carbon rods and by single laser ablation of a sintered germanium-carbon rod, and trapped in Ar matrices. Two vibrational fundamentals of linear GeC3, ?1(s) = 1903.9 cm-1 and ?2(s) = 1279.6 cm-1, have been observed. In the present work there is no spectroscopic evidence of cyclic structures for GeC3 with either the transannular Ge-C or C-C bond although at the coupled cluster level of theory they are both predicted to be ~7-9 kcal/mol lower in energy than the linear isomer. This result suggests a need for further theoretical studies of GeC3 to see if the cyclic isomers are indeed more stable than the linear.^New combination bands of carbon chains have been observed, (?1+?4) = 3388.8 cm-1 of linear C5 and (?2+?7) = 3471.8 cm-1 of linear C9.^Since the asymmetric stretching1 modes involved in these absorptions have been measured previously it has been possible to assign the infrared inactive symmetric stretching modes, the ?1(sg) mode of linear C5 at 1942 cm-1 and the ?2(sg) mode of linear C9 at 1870 cm-1. The ?1(sg) mode of linear C5 is the last undetected fundamental of this molecule. The ?6(su) weakest asymmetric stretching mode of linear C7 has been detected for the first time and has been assigned at 1100.1 cm-1 in solid Ar.^The calculation of the intensities of combination bands presented in this work suggests that the second derivatives computed numerically from the first derivatives are precise enough to predict intensities of combination/difference bands with magnitudes of order >~5 km/mol.^Therefore, computing the fundamentals intensities using the mechanical (up to the quartic term) and electrical (up to the second term) anharmonicity corrections might clarify why the intensity predictions using only the first dipole-moment derivatives with pure harmonic states are so inexact. To my knowledge, the inexactness of the calculated fundamental intensities is attributed to the method used for the calculation of the first derivatives of the dipole-moment rather than including anharmonic terms.
dc.format.mediumFormat: Onlineen_US
dc.language.isoengen_US
dc.publisher[Fort Worth, Tex.] : Texas Christian University,en_US
dc.relation.ispartofTexas Christian University dissertationen_US
dc.relation.ispartofUMI thesis.en_US
dc.relation.ispartofTexas Christian University dissertation.en_US
dc.relation.requiresMode of access: World Wide Web.en_US
dc.relation.requiresSystem requirements: Adobe Acrobat reader.en_US
dc.subject.lcshFourier transform infrared spectroscopy.en_US
dc.subject.lcshCluster theory (Nuclear physics)en_US
dc.subject.lcshGermanium.en_US
dc.subject.lcshCarbon.en_US
dc.titleInfrared spectroscopy and theoretical studies of group IV moleculesen_US
dc.typeTexten_US
etd.degree.departmentDepartment of Physics
etd.degree.levelDoctoral
local.collegeCollege of Science and Engineering
local.departmentPhysics and Astronomy
local.academicunitDepartment of Physics and Astronomy
dc.type.genreDissertation
local.subjectareaPhysics and Astronomy
etd.degree.nameDoctor of Philosophy
etd.degree.grantorTexas Christian University


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