Palladium-Catalyzed Allylation/Benzylation of H-Phosphinate Esters with Alcohols

Fers-Lidou, Anthony; Berger, Olivier; Montchamp, Jean-Luc

dc.creator	Fers-Lidou, Anthony
dc.creator	Berger, Olivier
dc.creator	Montchamp, Jean-Luc
dc.date.accessioned	2017-06-29T16:32:07Z
dc.date.available	2017-06-29T16:32:07Z
dc.date.issued	2016-09-28
dc.identifier.uri	https://doi.org/10.3390/molecules21101295
dc.identifier.uri	https://repository.tcu.edu/handle/116099117/19791
dc.identifier.uri	https://www.mdpi.com/1420-3049/21/10/1295
dc.description.abstract	The Pd-catalyzed direct alkylation of H-phosphinic acids and hypophosphorous acid with allylic/benzylic alcohols has been described previously. Here, the extension of this methodology to H-phosphinate esters is presented. The new reaction appears general, although its scope is narrower than with the acids, and its mechanism is likely different. Various alcohols are examined in their reaction with phosphinylidene compounds R1R2P(O)H.
dc.language.iso	en	en_US
dc.publisher	Multidisciplinary Digital Publishing Institute
dc.rights.uri	https://creativecommons.org/licenses/by/4.0/
dc.source	Molecules
dc.subject	palladium
dc.subject	cross-coupling
dc.subject	alcohols
dc.subject	H-phosphinate esters
dc.subject	allylation
dc.subject	benzylation
dc.title	Palladium-Catalyzed Allylation/Benzylation of H-Phosphinate Esters with Alcohols
dc.type	Article
dc.rights.holder	Fers-Lidou et al.
dc.rights.license	CC BY 4.0
local.college	College of Science and Engineering
local.department	Chemistry and Biochemistry
local.persons	All (CHEM)