Structure of a minor reaction product formed via base promoted hydrolysis of Thiele's ester

dc.creator	Watson, WH
dc.creator	Marchand, AP
dc.creator	Sivappa, R
dc.date.accessioned	2022-01-31T17:27:28Z
dc.date.available	2022-01-31T17:27:28Z
dc.date.issued	2004
dc.identifier.uri	https://doi.org/10.3998/ark.5550190.0005.307
dc.identifier.uri	https://repository.tcu.edu/handle/116099117/49964
dc.description.abstract	Base promoted hydrolysis of dimethyl 3aalpha,4alpha,7alpha,7aalpha-tetrahydro-4,7-methano-1H-indene-2,5-dicarboxylate (i.e., Thiele's ester, 2), performed by using KOH-MeOH, afforded after aqueous acidic workup the corresponding diacid (i.e., Thiele's acid, 1) along with a minor reaction product, 3. Compound 3 has been shown to possess structure 3a via application of single crystal X-ray crystallographic techniques.
dc.language.iso	en	en_US
dc.publisher	SpringerNature
dc.rights.uri	https://creativecommons.org/licenses/by/4.0/
dc.source	Arkivoc
dc.subject	Michael addition
dc.subject	selective ester hydrolysis
dc.subject	X-ray crystal structure determination
dc.title	Structure of a minor reaction product formed via base promoted hydrolysis of Thiele's ester
dc.type	Article
dc.rights.holder	Arkat Usa Inc
dc.rights.license	CC BY 4.0
local.college	College of Science and Engineering
local.department	Chemistry and Biochemistry
local.persons	Watson (CHEM)

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