Structure of a minor reaction product formed via base promoted hydrolysis of Thiele's esterShow full item record
| Title | Structure of a minor reaction product formed via base promoted hydrolysis of Thiele's ester |
|---|---|
| Author | Watson, WH; Marchand, AP; Sivappa, R |
| Date | 2004 |
| Abstract | Base promoted hydrolysis of dimethyl 3aalpha,4alpha,7alpha,7aalpha-tetrahydro-4,7-methano-1H-indene-2,5-dicarboxylate (i.e., Thiele's ester, 2), performed by using KOH-MeOH, afforded after aqueous acidic workup the corresponding diacid (i.e., Thiele's acid, 1) along with a minor reaction product, 3. Compound 3 has been shown to possess structure 3a via application of single crystal X-ray crystallographic techniques. |
| Link | https://doi.org/10.3998/ark.5550190.0005.307
https://repository.tcu.edu/handle/116099117/49964 |
| Department | Chemistry and Biochemistry |
| Subject | Michael addition
selective ester hydrolysis X-ray crystal structure determination |
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