Molecular Design Using Selected Concentration Effects in Optically Activated Fluorescent MatricesShow full item record
| Title | Molecular Design Using Selected Concentration Effects in Optically Activated Fluorescent Matrices |
|---|---|
| Author | Lewkowicz, Aneta; Walczewska-Szewc, Katarzyna; Czarnomska, Martyna; Gruszczynska, Emilia; Pierpaoli, Mattia; Bogdanowicz, Robert; Gryczynski, Zygmunt |
| Date | 4/28/2024 |
| Description | Molecular physics plays a pivotal role in various fields, including medicine, pharmaceuticals, and broader industrial applications. This study aims to enhance the methods for producing specific optically active materials with distinct spectroscopic properties at the molecular level, which are crucial for these sectors, while prioritizing human safety in both production and application. Forensic science, a significant socio-economic field, often employs hazardous substances in analyzing friction ridges on porous surfaces, posing safety concerns. In response, we formulated novel, non-toxic procedures for examining paper evidence, particularly thermal papers. Our laboratory model utilizes a polyvinyl alcohol polymer as a rigid matrix to emulate the thermal paper's environment, enabling precise control over the spectroscopic characteristics of 1,8-diazafluoro-9-one (DFO). We identified and analyzed the cyclodimer 1,8-diazafluoren-9-one (DAK DFO), which is a non-toxic and biocompatible alternative for revealing forensic marks. The reagents used to preserve fingerprints were optimized for their effectiveness and stability. Using stationary absorption and emission spectroscopy, along with time-resolved emission studies, we verified the spectroscopic attributes of the new structures under deliberate aggregation conditions. Raman spectroscopy and quantum mechanical computations substantiated the cyclodimer's configuration. The investigation provides robust scientific endorsement for the novel compound and its structural diversity, influenced by the solvatochromic sensitivity of the DFO precursor. Our approach to monitoring aggregation processes signifies a substantial shift in synthetic research paradigms, leveraging simple chemistry to yield an innovative contribution to forensic science methodologies. |
| Link | https://doi.org/10.3390/ijms25094804
https://repository.tcu.edu/handle/116099117/65972 |
| Department | Physics and Astronomy |
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- Research Publications [1008]
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